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Abstract Temperate exoplanets between the sizes of Earth and Neptune, known as “sub-Neptunes,” have emerged as intriguing targets for astrobiology. It is unknown whether these planets resemble Earth-like terrestrial worlds with a habitable surface, Neptune-like giant planets with deep atmospheres and no habitable surface, or something exotic in between. Recent JWST transmission spectroscopy observations of the canonical sub-Neptune, K2-18 b, revealed ~1% CH₄, ~1% CO₂, and a nondetection of CO in the atmosphere. While previous studies proposed that the observed atmospheric composition could help constrain the lower atmosphere's conditions and determine the interior structure of sub-Neptunes like K2-18 b, the possible interactions between the atmosphere and a hot, supercritical water ocean at its base remain unexplored. In this work, we investigate whether a global supercritical water ocean, resembling a planetary-scale hydrothermal system, can explain these observations on K2-18 b–like sub-Neptunes through equilibrium aqueous geochemical calculations. We find that the observed atmospheric CH₄/CO₂ratio implies a minimum ocean temperature of ~710 K, whereas the corresponding CO/CO₂ratio allows ocean temperatures up to ~1070 K. These results indicate that a global supercritical water ocean on K2-18 b is plausible. While life cannot survive in such an ocean, this work represents the first step toward understanding how a global supercritical water ocean may influence observable atmospheric characteristics on volatile-rich sub-Neptunes. Future observations with better-constrained CO and NH₃mixing ratios could further help distinguish between possible interior compositions of K2-18 b. 

Abstract Understanding the surface temperature and interior structure of cold-to-temperate sub-Neptunes is critical for assessing their habitability, yet direct observations are challenging. In this study, we investigate the impact of water condensation on the atmospheric compositions of sub-Neptunes, focusing on the implications for James Webb Space Telescope (JWST) spectroscopic observations. By modeling the atmospheric photochemistry of two canonical sub-Neptunes, K2-18 b and LHS 1140 b, both with and without water condensation and with and without thick atmospheres, we demonstrate that water condensation can significantly affect the predicted atmospheric compositions. This effect is driven by oxygen depletion from the condensation of water vapor and primarily manifests as an increase in the C/O ratio within the photochemically active regions of the atmosphere. This change in composition particularly affects planets with thin H₂-dominated atmospheres, leading to a transition in dominant nitrogen and carbon carriers from N₂and oxygen-rich species like CO/CO₂toward heavier hydrocarbons and nitriles. While our models do not fully account for the loss mechanisms of these higher-order species, such molecules can go on to form more refractory molecules or hazes. Planets with thin H₂-rich atmospheres undergoing significant water condensation are thus likely to exhibit very hazy atmospheres. The relatively flat JWST spectra observed for LHS 1140 b could be consistent with such a scenario, suggesting a shallow surface with extensive water condensation or a high atmospheric C/O ratio. Conversely, the JWST observations of K2-18 b are better aligned with a volatile-rich mini-Neptune with a thick atmosphere. 

Abstract Brown dwarf spectra offer vital testbeds for our understanding of the chemical and physical processes that sculpt substellar atmospheres. Recently, atmospheric retrieval approaches have been successfully applied to low-resolution (R∼ 100) spectra of L, T, and Y dwarfs, yielding constraints on the chemical abundances and temperature structures of these atmospheres. Medium-resolution (R∼ 10³) spectra of brown dwarfs offer additional insight, as molecular features are more easily disentangled and the thermal structure of the upper atmosphere is better probed. We present results from a GPU-based retrieval analysis of a high signal-to-noise, medium-resolution (R∼ 6000) FIRE spectrum from 0.85 to 2.5μm of the T9 dwarf UGPS J072227.51–054031.2. At 60× higher spectral resolution than previous brown dwarf retrievals, a number of novel challenges arise. We examine the effect of different opacity sources, in particular for CH₄. Furthermore, we find that flaws in the data like errors from order stitching can bias our constraints. We compare these retrieval results to those for anR∼ 100 spectrum of the same object, revealing how constraints on atmospheric abundances and temperatures improve by an order of magnitude or more with increased spectral resolution. In particular, we can constrain the abundance of H₂S, which is undetectable at lower spectral resolution. While these medium-resolution retrievals offer the potential of precise, stellar-like constraints on atmospheric abundances (∼0.02 dex), our retrieved radius is unphysically small ( $R={0.50}_{-0.01}^{+0.01}$R_Jup), indicating shortcomings with our modeling framework. This work is an initial investigation into brown dwarf retrievals at medium spectral resolution, offering guidance for future ground-based studies and JWST observations. 

Abstract A primary goal of exoplanet science is to measure the atmospheric composition of gas giants in order to infer their formation and migration histories. Common diagnostics for planet formation are the atmospheric metallicity ([M/H]) and the carbon-to-oxygen (C/O) ratio as measured through transit or emission spectroscopy. The C/O ratio in particular can be used to approximately place a planet’s initial formation radius from the stellar host, but a given C/O ratio may not be unique to formation location. This degeneracy can be broken by combining measurements of both the C/O ratio and the atmospheric refractory-to-volatile ratio. We report the measurement of both quantities for the atmosphere of the canonical ultrahot Jupiter WASP-121 b using the high-resolution (R= 45,000) IGRINS instrument on Gemini South. Probing the planet’s direct thermal emission in both pre- and post-secondary eclipse orbital phases, we infer that WASP-121 b has a significantly superstellar C/O ratio of ${0.70}_{-0.10}^{+0.07}$and a moderately superstellar refractory-to-volatile ratio at ${3.83}_{-1.67}^{+3.62}\times$stellar. This combination is most consistent with formation between the soot line and H₂O snow line, but we cannot rule out formation between the H₂O and CO snow lines or beyond the CO snow line. We also measure velocity offsets between H₂O, CO, and OH, potentially an effect of chemical inhomogeneity on the planet dayside. This study highlights the ability to measure both C/O and refractory-to-volatile ratios via high-resolution spectroscopy in the near-IRHandKbands. 

Abstract The coldest Y spectral type brown dwarfs are similar in mass and temperature to cool and warm (∼200–400 K) giant exoplanets. We can therefore use their atmospheres as proxies for planetary atmospheres, testing our understanding of physics and chemistry for these complex, cool worlds. At these cold temperatures, their atmospheres are cold enough for water clouds to form, and chemical timescales increase, increasing the likelihood of disequilibrium chemistry compared to warmer classes of planets. JWST observations are revolutionizing the characterization of these worlds with high signal-to-noise, moderate-resolution near- and mid-infrared spectra. The spectra have been used to measure the abundances of prominent species, like water, methane, and ammonia; species that trace chemical reactions, like carbon monoxide; and even isotopologues of carbon monoxide and ammonia. Here, we present atmospheric retrieval results using both published fixed-slit (Guaranteed Time Observation program 1230) and new averaged time series observations (GO program 2327) of the coldest known Y dwarf, WISE 0855–0714 (using NIRSpec G395M spectra), which has an effective temperature of ∼264 K. We present a detection of deuterium in an atmosphere outside of the solar system via a relative measurement of deuterated methane (CH₃D) and standard methane. From this, we infer the D/H ratio of a substellar object outside the solar system for the first time. We also present a well-constrained part-per-billion abundance of phosphine (PH₃). We discuss our interpretation of these results and the implications for brown dwarf and giant exoplanet formation and evolution. 

Abstract Young exoplanets are attractive targets for atmospheric characterization to explore the early phase of planetary evolution and the surrounding environment. Recent observations of the 10 Myr young Neptune-sized exoplanet K2-33b revealed that the planet’s transit depth drastically decreases from the optical to near-infrared wavelengths. Thao et al. suggested that a thick planetary haze and/or stellar spots may be the cause; however, even the best-fit model only barely explains the data. Here, we propose that the peculiar transmission spectrum may indicate that K2-33b possesses a circumplanetary dust ring; an analog of Jupiter’s dust ring. We demonstrate that the ring could produce a steep slope in the transmission spectrum even if its optical depth is as low as ∼10 −2 . We then apply a novel joint atmosphere-ring retrieval to K2-33b and find that the ring scenario could well explain the observed spectrum for various possible ring compositions. Importantly, the dust ring also exhibits prominent ring particle absorption features of ring particles around ∼10 μ m, whose shape and strength depend on the composition of the ring. Thus, future observations by JWST-MIRI would be able to test not only the ring hypothesis but also, if it indeed exists, to constrain the composition of the ring—providing a unique opportunity to explore the origins of the dust ring around its parent planet, soon after the planetary system’s formation. 

Abstract About 70%–80% of stars in our solar and Galactic neighborhood are M dwarfs. They span a range of low masses and temperatures relative to solar-type stars, facilitating molecule formation throughout their atmospheres. Standard stellar atmosphere models primarily designed for FGK stars face challenges when characterizing broadband molecular features in spectra of cool stars. Here, we introduce SPHINX —a new 1D self-consistent radiative–convective thermochemical equilibrium chemistry model grid of atmospheres and spectra for M dwarfs in low resolution ( R ∼ 250). We incorporate the latest precomputed absorption cross sections with pressure broadening for key molecules dominant in late-K, early/main-sequence-M stars. We then validate our grid models by determining fundamental properties ( T eff , log g , [M/H], radius, and C/O) for 10 benchmark M+G binary stars with known host metallicities and 10 M dwarfs with interferometrically measured angular diameters. Incorporating the Gaussian process inference tool Starfish , we account for correlated and systematic noise in low-resolution (spectral stitching of SpeX, SNIFS, and STIS) observations and derive robust estimates of fundamental M-dwarf atmospheric parameters. Additionally, we assess the influence of photospheric heterogeneity on inferred [M/H] and find that it could explain some deviations from observations. We also probe whether the adopted convective mixing length parameter influences inferred radii, effective temperature, and [M/H] and again find that may explain discrepancies between interferometric observations and model-derived parameters for cooler M dwarfs. Mainly, we show the unique strength in leveraging broadband molecular absorption features occurring in low-resolution M dwarf spectra and demonstrate the ability to improve constraints on fundamental properties of exoplanet hosts and brown-dwarf companions. 

Abstract We study the constraining power of a high-precision measurement of the gravity field for Uranus and Neptune, as could be delivered by a low-periapse orbiter. Our study is practical, assessing the possible deliverables and limitations of such a mission with respect to the structure of the planets. Our study is also academic, assessing in a general way the relative importance of the low-order gravity, high-order gravity, rotation rate, and moment of inertia (MOI) in constraining planetary structure. We attempt to explore all possible interior density structures of a planet that are consistent with hypothetical gravity data via MCMC sampling of parameterized density profiles. When the gravity field is poorly known, as it is today, uncertainties in the rotation rate on the order of 10 minutes are unimportant, as they are interchangeable with uncertainties in the gravity coefficients. By the same token, when the gravity field is precisely determined, the rotation rate must be known to comparable precision. When gravity and rotation are well known, the MOI becomes well constrained, limiting the usefulness of independent MOI determinations unless they are extraordinarily precise. For Uranus and Neptune, density profiles can be well constrained. However, the nonuniqueness of the relative roles of H/He, watery volatiles, and rock in the deep interior will still persist with high-precision gravity data. Nevertheless, the locations and magnitudes (in pressure space) of any large-scale composition gradient regions can likely be identified, offering a crucially better picture of the interiors of Uranus or Neptune. 

Abstract AF Lep A+b is a remarkable planetary system hosting a gas-giant planet that has the lowest dynamical mass among directly imaged exoplanets. We present an in-depth analysis of the atmospheric composition of the star and planet to probe the planet’s formation pathway. Based on new high-resolution spectroscopy of AF Lep A, we measure a uniform set of stellar parameters and elemental abundances (e.g., [Fe/H] = −0.27 ± 0.31 dex). The planet’s dynamical mass ( ${2.8}_{-0.5}^{+0.6}$M_Jup) and orbit are also refined using published radial velocities, relative astrometry, and absolute astrometry. We usepetitRADTRANSto perform chemically consistent atmospheric retrievals for AF Lep b. The radiative–convective equilibrium temperature profiles are incorporated as parameterized priors on the planet’s thermal structure, leading to a robust characterization for cloudy self-luminous atmospheres. This novel approach is enabled by constraining the temperature–pressure profiles via the temperature gradient $\left(d\ln T/d\ln P\right)$, a departure from previous studies that solely modeled the temperature. Through multiple retrievals performed on different portions of the 0.9–4.2μm spectrophotometry, along with different priors on the planet’s mass and radius, we infer that AF Lep b likely possesses a metal-enriched atmosphere ([Fe/H] > 1.0 dex). AF Lep b’s potential metal enrichment may be due to planetesimal accretion, giant impacts, and/or core erosion. The first process coincides with the debris disk in the system, which could be dynamically excited by AF Lep b and lead to planetesimal bombardment. Our analysis also determinesT_eff≈ 800 K, $\log \left(g\right)\approx 3.7$dex, and the presence of silicate clouds and disequilibrium chemistry in the atmosphere. Straddling the L/T transition, AF Lep b is thus far the coldest exoplanet with suggested evidence of silicate clouds. 

ABSTRACT We present Gemini South/IGRINS observations of the 1060 K T6 dwarf 2MASS J08173001−6155158 with unprecedented resolution ($$R\equiv \lambda /\Delta \lambda =45\, 000$$) and signal-to-noise ratio (S/N > 200) for a late-type T dwarf. We use this benchmark observation to test the reliability of molecular line lists used up-to-date atmospheric models. We determine which spectroscopic regions should be used to estimate the parameters of cold brown dwarfs and, by extension, exoplanets. We present a detailed spectroscopic atlas with molecular identifications across the H and K bands of the near-infrared. We find that water (H2O) line lists are overall reliable. We find the most discrepancies amongst older methane (CH4) line lists, and that the most up-to-date CH4 line lists correct many of these issues. We identify individual ammonia (NH3) lines, a hydrogen sulfide (H2S) feature at 1.5900 $$\mu$$m, and a molecular hydrogen (H2) feature at 2.1218 $$\mu$$m. These are the first unambiguous detections of H2S and H2 absorption features in an extra-solar atmosphere. With the H2 detection, we place an upper limit on the atmospheric dust concentration of this T6 dwarf: at least 500 times less than the interstellar value, implying that the atmosphere is effectively dust-free. We additionally identify several features that do not appear in the model spectra. Our assessment of the line lists is valuable for atmospheric model applications to high-dispersion, low-S/N, high-background spectra, such as an exoplanet around a star. We demonstrate a significant enhancement in the detection of the CH4 absorption signal in this T6 dwarf with the most up-to-date line lists.